Densities and viscosities of binary system containing 1,3-dimethylimidazolium dimethylphosphate and dimethyl sulfoxide or acetonitrile

WANG Xinxin1 ZHOU Qing1,2 ZHANG Xiaochun1 ZHANG Zhibo1 LYU Xingmei1,2 ZHANG Suojiang1,2

(1.Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China 100190)
(2.College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, China 100049)
【Knowledge Link】ionic liquid

【Abstract】Due to their special structure and properties, ionic liquids (ILs) have shown good results in the application of cellulose pretreatment. Relevant physical property data are indispensable in promoting the industrialization of ILs. In this study, IL 1,3-dimethylimidazolium dimethylphosphate ([Mmim][DMP]) was synthesized and the densities and viscosities of the binary systems of [Mmim][DMP] with dimethylsulfoxide (DMSO) or acetonitrile were measured in the temperature range from 293.15 K to 323.15 K over the whole concentration. Then volume properties and excess property data were calculated and fitted. Based on the data of apparent molar volume , apparent molar volume at infinite dilution , partial molar volume, excess molar volume VE, and molecular simulation results, the influence of the interaction between IL and solvents and hydrogen bonds formed between IL and DMSO (or acetonitrile) were analyzed.

【Keywords】 ionic liquids; DMSO; acetonitrile; density; viscosity;

【DOI】

【Funds】 National Natural Science Foundation of China (21890760, 21978291, 21776289, 51674234, 21878292)

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(Translated by WANG YX)

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This Article

ISSN:0438-1157

CN: 11-1946/TQ

Vol 71, No. 01, Pages 177-191

January 2020

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Abstract

  • Introduction
  • 1 Experimental materials and methods
  • 2 Results and discussion
  • 3 Conclusions
  • Symbols
  • References