Preparation of thin-film composite nanofiltration membranes with amino-functionalized graphene oxide by interfacial polymerization

ZHANG Runnan1,2 LI Yafei1,2 SU Yanlei1,2 JIANG Zhongyi1,2

(1.School of Chemical Engineering and Technology, Tianjin University, Tianjin, China 300072)
(2.Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) , Tianjin, China 300072)

【Abstract】A series of thin-film composite (TFC) nanofiltration (NF) membranes were prepared by interfacial polymerization, using amino-functionalized graphene oxide (NGO) as the aqueous monomer. Fourier transform infrared spectrometer (FTIR), X-ray photoelectron spectrometer (XPS), transmission electron microscope (TEM), scanning electron microscope (SEM) and atomic force microscope (AFM) were applied to measure the chemical compositions and morphologies of the prepared NGO and TFC NF membranes. The effect of NGO and trimesoyl chloride (TMC) concentrations on the separation performance of the TFC NF membranes was investigated systematically. The TFC NF membrane exhibited a high flux of 27.8 L·m−2·h−1 under a relatively low operation pressure (0.2 MPa) and an excellent dye/salt separation performance with high rejections for organic dyes (methyl orange of 74.8%, orange G Ⅱ of 96.0%, Congo red of 98.5% and methyl blue of 99%) and low rejections for inorganic salts (Na2SO4 of 21.4%, MgSO4 of 10.7%, NaCl of 5.3% and MgCl2 of 1.5%). In addition, the TFC NF membrane showed good long term operational stability as well as a satisfying antifouling performance against bovine serum albumin (BSA).

【Keywords】 amino-functionalized graphene oxide; interfacial polymerization; membrane; nanofiltration; preparation;

【DOI】

【Funds】 National Key Research and Development Program of China (2016YFB0600503)

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(Translated by KANG GD)

    References

    [1] HAN J N, YANG D L, ZHANG S H, et al. Study on dye desalting by PPES hollowfiber nanofiltration membrane [J]. Technology of Water Treatment, 2013, 39 (10): 118–121 (in Chinese).

    [2] HUANG J, SHU Z N, ZHANG S H. Fabrication of high flux polyethersulfone nanofiltration membrane for dye concentration and desalination [J]. CIESC Journal, 2014, 65 (10): 3968–3975 (in Chinese).

    [3] LIN J, YE W, BALTARU M C, et al. Tight ultrafiltration membranes for enhanced separation of dyes and Na2SO4 during textile wastewater treatment [J]. Journal of Membrane Science, 2016, 514: 217–228.

    [4] ZHU J, ZHANG Y, TIAN M, et al. Fabrication of a mixed matrix membrane with in situ synthesized quaternized polyethylenimine nanoparticles for dye purification and reuse [J]. ACS Sustainable Chemistry&Engineering, 2015, 3 (4): 690–701.

    [5] ZHANG R, SU Y, ZHAO X, et al. A novel positively charged composite nanofiltration membrane prepared by bio-inspired adhesion of polydopamine and surface grafting of poly (ethylene imine) [J]. Journal of Membrane Science, 2014, 470: 9–17.

    [6] ZHANG Y, SU Y, PENG J, et al. Composite nanofiltration membranes prepared by interfacial polymerization with natural material tannic acid and trimesoyl chloride [J]. Journal of Membrane Science, 2013, 429: 235–242

    [7] SONG Y F, ZHAO G, LI T M, et al. Influence of feedwater quality on nanofiltration membrane softening efficiencies for brackish water in long-term operation [J]. CIESC Journal, 2017, 68 (8): 3133–3140 (in Chinese).

    [8] WANG L, JI S, WANG N, et al. One-step self-assembly fabrication of amphiphilic hyperbranched polymer composite membrane from aqueous emulsion for dye desalination [J]. Journal of Membrane Science, 2014, 452: 143–151.

    [9] ZHU J, TIAN M, ZHANG Y, et al. Fabrication of a novel “loose” nanofiltration membrane by facile blending with chitosan–montmorillonite nanosheets for dyes purification [J]. Chemical Engineering Journal, 2015, 265: 184–193.

    [10] YU L, ZHANG Y, ZHANG H, et al. Development of a molecular separation membrane for efficient separation of low-molecular-weight organics and salts [J]. Desalination, 2015, 359: 176–185.

    [11] YU L, ZHANG Y, WANG Y, et al. High flux, positively charged loose nanofiltration membrane by blending with poly (ionic liquid) brushes grafted silica spheres [J]. Journal of Hazardous Materials, 2015, 287: 373–383.

    [12] YANG Z S, ZHANG L, ZHANG G H, et al. Preparation and characterization of polyimide/polypropylene solvent resistant nanofiltration composite membrane via interfacial polymerization [J]. CIESC Journal, 2012, 63 (8): 2635–3641 (in Chinese).

    [13] GAO K, XU Z H, HONG Y B, et al. Layer-by-layer self-assembly preparation and performance of GO–ceramics composite nanofiltration membrane [J]. CIESC Journal, 2017, 68 (5): 2177–2185 (in Chinese).

    [14] ZHANG R, SU Y, ZHOU L, et al. Manipulating the multifunctionalities of polydopamine to prepare high-flux anti-biofouling composite nanofiltration membranes [J]. RSC Adv., 2016, 6 (39): 32863–32873.

    [15] LI X, CHEN Y, HU X, et al. Desalination of dye solution utilizing PVA/PVDF hollow fiber composite membrane modified with TiO2 nanoparticles [J]. Journal of Membrane Science, 2014, 471: 118–129.

    [16] GOHIL J M, RAY P. A review on semi-aromatic polyamide TFC membranes prepared by interfacial polymerization: potential for water treatment and desalination [J]. Separation and Purification Technology, 2017, 181: 159–182.

    [17] LI Y, SU Y, ZHAO X, et al. Preparation of antifouling nanofiltration membrane via interfacial polymerization of fluorinated polyamine and trimesoyl chloride [J]. Industrial&Engineering Chemistry Research, 2015, 54 (33): 8302–8310.

    [18] PENG J, SU Y, CHEN W, et al. Polyamide nanofiltration membrane with high separation performance prepared by EDC/NHS mediated interfacial polymerization [J]. Journal of Membrane Science, 2013, 427: 92–100.

    [19] LI H Y, ZHAI D, ZHOU Y, et al. Polyamide composite NF membrane modified with polyaniline nanoparticles [J]. CIESC Journal, 2015, 66 (1): 142–148 (in Chinese).

    [20] WENG X, JI Y, ZHAO F, et al. Tailoring the structure of polyamide thin film composite membrane with zwitterions to achieve high water permeability and antifouling property [J]. RSC Adv., 2015, 5 (120): 98730–98739.

    [21] ZHOU C, SHI Y, SUN C, et al. Thinfilm composite membranes formed by interfacial polymerization with natural material sericin and trimesoyl chloride for nanofiltration [J]. Journal of Membrane Science, 2014, 471: 381–391.

    [22] LAU W J, GRAY S, MATSUURA T, et al. A review on polyamide thin film nanocomposite (TFN) membranes: history, applications, challenges and approaches [J]. Water Research, 2015, 80: 306–324.

    [23] ZHANG Q, FAN L, YANG Z, et al. Loose nanofiltration membrane for dye/salt separation through interfacial polymerization with in-situ generated TiO2 nanoparticles [J]. Applied Surface Science, 2017, 410: 494–504.

    [24] BANO S, MAHMOOD A, KIM S J, et al. Graphene oxide modified polyamide nanofiltration membrane with improved flux and antifouling properties [J]. Journal of Materials Chemistry A, 2015, 3 (5): 2065–2071.

    [25] KIM H J, CHOI Y S, LIM M Y, et al. Reverse osmosis nanocomposite membranes containing graphene oxides coated by tannic acid with chlorine-tolerant and antimicrobial properties [J]. Journal of Membrane Science, 2016, 514: 25–34.

    [26] WEN P, CHEN Y, HU X, et al. Polyamide thin film composite nanofiltration membrane modified with acyl chlorided graphene oxide [J]. Journal of Membrane Science, 2017, 535: 208–220.

    [27] PERREAULT F, TOUSLEY M E, ELIMELECH M. Thin-film composite polyamide membranes functionalized with biocidal graphene oxide nanosheets [J]. Environmental Science & Technology Letters, 2014, 1 (1): 71–76.

    [28] WAN W B, ZHAO Z B, FAN Y R, et al. Graphene derivatives: synthesis and applications [J]. Progress in Chemistry, 2011, 23 (9): 1883–1891 (in Chinese).

    [29] WAN W, LI L, FAN Y, et al. Ultrafast fabrication of covalently cross-linked multifunctional graphene oxide monoliths [J]. Advanced Functional Materials, 2014, 24 (31): 4915–4921.

    [30] CHOI W, CHOI J, BANG J, et al. Layer-by-layer assembly of graphene oxide nanosheets on polyamide membranes for durable reverse-osmosis applications [J]. ACS Applied Materials and Interfaces, 2013, 5 (23): 12510–12519.

    [31] ZHANG R, LI Y, SU Y, et al. Engineering amphiphilic nanofiltration membrane surfaces with a multi-defense mechanism for improved antifouling performances [J]. Journal of Materials Chemistry A, 2016, 4 (20): 7892–7902.

    [32] LI Y, SU Y, ZHAO X, et al. Surface fluorination of polyamide nanofiltration membrane for enhanced antifouling property [J]. Journal of Membrane Science, 2014, 455: 15–23.

    [33] LI Y, SU Y, ZHAO X, et al. Antifouling, high-flux nanofiltration membranes enabled by dual functional polydopamine [J]. ACS Applied Materials and Interfaces, 2014, 6 (8): 5548–5557.

    [34] HOFFER E, KEDEM O. Hyperfiltration in charged membranes: the fixed charge model [J]. Desalination, 1967, 2: 25–39.

    [35] ZHANG R, LIU Y, HE M, et al. Antifouling membranes for sustainable water purification: strategies and mechanisms [J]. Chemical Society Reviews, 2016, 45 (21): 5888–5924.

    [36] WERBER J R, OSUJI C O, ELIMELECH M. Materials for next-generation desalination and water purification membranes [J]. Nature Reviews Materials, 2016, 1 (5): 1–15.

    [37] LEE A, ELAM J W, DARLING S B. Membrane materials for water purification: design, development, and application [J]. Environmental Science—Water Research & Technology, 2016, 2 (1): 17–42.

    [38] MANSOURI J, HARRISSON S, CHEN V. Strategies for controlling biofouling in membrane filtration systems: challenges and opportunities [J]. Journal of Materials Chemistry, 2010, 20 (22): 4567–4586.

    [39] RANA D, MATSUURA T. Surface modifications for antifouling membranes [J]. Chemical Reviews, 2010, 110 (4): 2448–2471.

    [40] LU X, ARIAS CHAVEZ L H, ROMERO-VARGAS CASTRILLON S, et al. Influence of active layer and support layer surface structures on organic fouling propensity of thin-film composite forward osmosis membranes [J]. Environmental Science & Technology, 2015, 49 (3): 1436–1444.

This Article

ISSN:1002-8870

CN: 11-1262/F

Vol , No. 08, Pages 2-14

August 2016

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Article Outline

Abstract

  • Introduction
  • 1 Experimental materials and method
  • 2 Results and discussion
  • 3 Conclusions
  • Symbol description
  • References